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许运华 教授

先进高分子材料研究所

电话: 022-27402307

Email: yunhua.xu@tju.edu.cn

研究所: 先进高分子材料研究所

个人简历

教育背景:

1998.9–2002.6 郑州大学 学士

2002.9–2008.6 华南理工大学 博士.

工作经历:

2006.12–2009.7 美国加州大学圣巴巴拉分校, 交换学生、博士后

2009.9–2015.5美国马里兰大学,访问学者、研究助理、助理研究员

2014.2–2014.7 美国爱荷华州立大学,研究助理

2015.7–天津大学材料学院,研究员,博士生导师.

研究方向

研究领域:

(1)能量储存和转化,包括锂离子电池、钠离子电池、锂-硫电池、锂-空电池、全固态电池和超级电容器等

(2)纳米材料及其在储能系统中的应用

(3)有机功能材料及其在储能系统中的应用

(4)储能电化学过程

承担项目

主要承担项目:

1.新型纳微多孔碳/硫复合正极材料的制备及其性能研究,基金委面上项目,2017-2020。

2.高性能锂-硫电池碳/硫复合正极材料的制备及其性能研究,天津市科委面上项目,2016-2019。

标志性成果

主要学术成就、获奖及荣誉:

主要从事储能材料和有机光电材料及器件等前沿技术的研究与开发,做出了系列原创性成果,具有坚实的研究基础和丰富的研究经验。已发表论文60余篇,其中20余篇发表在影响因子大于10的一流学术期刊上。论文被他人引用4500余次,多篇论文被Web of Science列为热点和高被引论文(至2017年11月)。获授权中国专利4项,美国专利两项。获得主要荣誉和奖励包括:

2010 全国优秀博士学位论文

2010 Ellen Williams Distinguished Postdoctoral Fellowship (美国马里兰大学)

2009 广东省科学技术一等奖

2009 广东省优秀博士学位论文

2009 华南理工大学优秀博士学位论文

2007 南粤优秀研究生(广东省)

2005 华南理工大学优秀博士生基金

2002 郑州大学优秀毕业生

发表文章、专利、专著(代表作):

36. Lingjun Kong, Ming Zhong, Wei Shuang, Yunhua Xu, Xian-He Bu,* Electrochemical sites inside crystalline porous materials for energy storage and conversion, Chemical Society Reviews, accepted.

35. Jixing Yang,* Zhuanping Wang, Yeqing Shi, Pengfei Sun, Yunhua Xu,* Poorly soluble 2,6-dimethoxy-9,10-anthraquinone cathode for lithium-ion batteries: the role of electrolyte concentration, ACS Applied Materials & Interfaces, DOI: 10.1021/acsami.9b19623.

34. Jixing Yang,* Hai Su, Zhuanping Wang, Pengfei Sun, Yunhua Xu,* An insoluble anthraquinone dimer with near-plane structure as a cathode material for lithium-ion batteries, ChemSusChem, DOI:10.1002/cssc.201903227.

33. Jixing Yang,* Peixun Xiong, Yeqing Shi, Pengfei Sun, Zhuanping Wang, Zifeng Chen, Yunhua Xu,* Rational molecular design of benzoquinone-derived cathode materials for high performance lithium-ion batteries, Advanced Functional Materials, DOI: 10.1002/adfm.201909597.

32. Xinxin Zhao, Fengjiao Chen, Junqing Liu, Mingren Cheng, Hai Su, Jianbo Liu, Yunhua Xu,* Enhanced surface binding energy regulates uniform potassium deposition for stable potassium metal anode, Journal of Materials Chemistry A, DOI: 10.1039/C9TA14226F.

31. Qiang Jiang, Peixun Xiong, Jingjuan Liu, Zhen Xie, Xiao-Qing Yang, Enyuan Hu,* Yunhua Xu,* Long Chen,* Redox-active 2D metal-organic framework cathodes with extraordinary high capacity, Angewandte Chemie International Edition, DOI: 10.1002/anie.201914395.

30. Peixun Xiong, Junxiu Wu, Mengfan Zhou, Yunhua Xu,* Bismuth-antimony alloy nanoparticle@porous carbon nanosheet composite anode for high performance potassium-ion batteries, ACS Nano, 14, 1018, 2020.

29. Zongmin Hu, Hai Su, Shuibin Tu, Peixun Xiong, Mingren Cheng, Xinxin Zhao, Liang Wang, Yumei Zhu, Fang Li,* Yunhua Xu,* Efficient polysulfide trapping enabled by a polymer adsorbent for high performance lithium-sulfur batteries, Electrochim Acta, 336, 135693, 2020.

28. Yeqing Shi, Pengfei Sun, Jixing Yang,* Yunhua Xu,* Benzoquinone- and naphthoquinone-bearing polymers synthesized by ring-opening metathesis polymerization as cathode materials for lithium-ion batteries, ChemSusChem, 13, 334, 2020.

27. Pengfei Sun, Panxing Bai, Zifeng Chen, Hai Su, Jixing Yang, Kang Xu, Yunhua Xu,* A lithium-organic primary battery, Small, 16, 1906462, 2020.

26. Panxing Bai, Xinpeng Han, Yongwu He, Peixun Xiong, Yufei Zhao, Jie Sun,* Yunhua Xu,* Solid electrolyte interphase manipulation towards highly stable hard carbon anodes for sodium ion batteries, Energy Storage Materials, 25, 324, 2020.

25. Mingren Cheng, Hai Su, Peixun Xiong, Xinxin Zhao, Yunhua Xu,* Molten lithium-filled three-dimensional hollow carbon tube mats for stable lithium metal anodes, ACS Applied Energy Materials, 2, 8303, 2019.

24. Jixing Yang,* Yeqing Shi, Pengfei Sun, Peixun Xiong, Yunhua Xu,* Optimization of molecular structure and electrode architecture of anthraquinone containing polymer cathode for high performance lithium-ion batteries, ACS Applied Materials & Interfaces, 11, 42305, 2019.

23. Chao Yang, Fan Lv, Yelong Zhang, Kang Dong, Hai Su, Feili Lai, Wei Wang, Yunhua Xu,* André Hilger, Yizhou Zhu,* Yanan Chen,* Yida Deng, Ingo Manke, Wenbin Hu, Confined Fe2VO4nitrogen-doped carbon nanowires with internal void space for high-rate and ultrastable potassium-ion storage, Advanced Energy Materials, 9, 1902674, 2019.

22. Peixun Xiong, Panxing Bai, Ang Li, Benfang Li, Mingren Cheng, Yiping Chen, Shuping Huang, Qiang Jiang, Xian-he Bu, Yunhua Xu,* Bismuth nanoparticle@carbon composite anodes for ultralong cycle life and high rate sodium-ion batteries, Advanced Materials, 31, 1904771, 2019.

21. Wei Shuang, Hui Huang, Lingjun Kong, Ming Zhong, Ang Li, Danhong Wang,* Yunhua Xu, Xian-He Bu,* Nitrogen-doped carbon shell-confined Ni3S2 composite nanosheets derived from Ni-MOF for high performance sodium-ion battery anodes, Nano Energy, 62, 154, 2019.

20. Shuibin Tu, Xinxin Zhao, Mingren Cheng, Pengfei Sun, Yongwu He, Yunhua Xu,* Uniform mesoporous MnO2 nanospheres as a surface chemical adsorption and physical confinement polysulfide mediator for lithiumsulfur batteries, ACS Applied Materials & Interfaces, 11, 10624, 2019.

19. Peixun Xiong, Xinpeng Han, Xinxin Zhao, Panxing Bai, Yang Liu, Jie Sun, Yunhua Xu,* Room temperature potassium-sulfur batteries enabled by microporous carbon stabilized small-molecule sulfur cathodes, ACS Nano, 13(2), 2536-2543, 2019.

18. Chong Zhang, Yu Qiao, Peixun Xiong, Wenyan Ma, Panxing Bai, Xue Wang, Qi Li, Jin Zhao, Yunfeng Xu, Yu Chen, Jing Hui Zeng, Feng Wang, Yunhua Xu,* Jia-Xing Jiang,* Conjugated microporous polymers with tunable electronic structure for high performance potassium-ion batteries, ACS Nano, 13, 745-754, 2019.

17. Benfang Li, Jin Zhao, Zihe Zhang, Chen Zhao, Pengfei Sun, Panxing Bai, Jixing Yang, Zhen Zhou,* Yunhua Xu,* Electrolyte-regulated solid-electrolyte interphase enables long cycle life performance in organic cathodes for potassium-ion batteries, Advanced Functional Materials, 29, 1807137, 2019.

16. Yongwu He, Panxing Bai, Shuyan Gao,* Yunhua Xu,* The marriage of an ether-based electrolyte with hard carbon anodes creates superior sodium-ion batteries with high mass loading, ACS Applied Materials & Interfaces, 10, 21380, 2018.

15. Yichun Wang, Xin Zhang, Peixun Xiong, Fuxing Yin, Yunhua Xu, Biao Wan, Qingzhou Wang, Gongkai Wang,* Puguang Ji,* Huiyang Gou,* Insight into the intercalation mechanism of WSe2 onions toward metal ion capacitors: sodium rivals lithium, Journal of Materials Chemistry A, 6, 21605, 2018.

14. Honglin Luo, Peixun Xiong, Jing Xie, Zhiwei Yang, Yuan Huang, Jimin Hu,* Yizao Wan,* Yunhua Xu,* Uniformly dispersed free-standing carbon nanofiber/graphene electrodes made by a scalable biological method for high-performance flexible supercapacitors, Advanced Functional Materials, 28, 1803075, 2018.

13. Shuibin Tu, Xiang Chen, Xinxin Zhao, Mingren Cheng, Peixun Xiong, Yongwu He, Qiang Zhang,* Yunhua Xu,* A polysulfide-immobilizing polymer retards the shuttle of polysulfide intermediates in lithium-sulfur batteries, Advanced Materials, 30, 1804581, 2018.

12. Qiang Jiang, Yusen Li, Xinxin Zhao, Peixun Xiong, Xiang Yu, Yunhua Xu,* Long Chen,* Inverse-vulcanization of vinylic functionalized covalent organic frameworks as efficient cathode materials for Li-S batteries, Journal of Materials Chemistry A, 6, 17977, 2018.

11. Peixun Xiong, Panxing Bai, Shuibin Tu, Mingren Cheng, Jinfeng Zhang, Jie Sun, Yunhua Xu,* Red phosphorus nanoparticle@3D interconnected carbon nanosheet framework composite for potassium-ion battery anodes, Small, 14, 1802140, 2018.

10. Xinxin Zhao, Yifan Tang, Chaolun Ni, Jiangwei Wang,* Alexander Star,* Yunhua Xu,* Free-standing nitrogen-doped cup-stacked carbon nanotube mats for potassium-ion battery anodes, ACS Applied Energy Materials, 1, 1703, 2018.

9. Panxing Bai, Yongwu He, Peixun Xiong, Xinxin Zhao, Kang Xu,* Yunhua Xu,* Long cycle life and high rate sodium-ion chemistry for hard carbon anodes, Energy Storage Materials, 13, 274, 2018.

8. Panxing Bai, Yongwu He, Xiaoxi Zou, Xinxin Zhao, Peixun Xiong, Yunhua Xu,* Elucidation of the sodium-storage mechanism in hard carbons, Advanced Energy Materials, 8, 1703217, 2018.

7. Chong Zhang, Yongwu He, Pan Mu, Xue Wang, Qian He, Yu Chen, Jinghui Zeng, Feng Wang, Yunhua Xu,* Jia-Xing Jiang,* Toward high performance thiophene-containing conjugated microporous polymer anodes for lithium-ion batteries through structure design, Advanced Functional Materials, 28, 1705432, 2018.

6. Peixun Xiong, Xinxin Zhao, Yunhua Xu,* Nitrogen-doped carbon nanotubes derived from metal-organic frameworks for potassium-ion battery anodes, ChemSusChem, 11, 202, 2018.

5. Jin Zhao, Jixing Yang, Pengfei Sun, Yunhua Xu,* Sodium sulfonate groups substituted anthraquinone as an organic cathode for potassium batteries, Electrochemistry Communications, 86, 34, 2018.

4. Xinxin Zhao, Peixun Xiong, Jianfang Meng, Yanqin Liang, Jiangwei Wang, Yunhua Xu,* High rate and long cycle life porous carbon nanofiber paper anodes for potassium-ion batteries, Journal of Materials Chemistry A, 5, 19237, 2017.

3. Xiaoxi Zou, Peixun Xiong, Jin Zhao, Jimin Hu, Zhitian Liu,* Yunhua Xu,* Recent research progress in non-aqueous potassium-ion batteries, Physical Chemistry Chemical Physics, 19, 26495, 2017.

2. Qiannan Wang, Xinxin Zhao, Chaolun Ni, He Tian, Jixue Li, Ze Zhang, Scott X. Mao, Jiangwei Wang,* Yunhua Xu,* Reaction and capacity fading mechanisms of tin nanoparticles in potassium-ion batteries, Journal of Physical Chemistry C, 121, 12652, 2017.

1. Jin Zhao, Xiaoxi Zou, Yujie Zhu, Yunhua Xu,* Chunsheng Wang, Electrochemical intercalation of potassium into graphite, Advanced Functional Materials, 26, 8103, 2016.