耿延候 教授
Email: yanhou.geng@tju.edu.cn
研究所：先进高分子材料研究所
地址：天津市津南区海河教育园雅观路135号53号楼305室
工作经历：
· 2015.12-现在， 天津大学材料科学与工程学院，教授、博士生导师
· 2003.09-2015.11，中国科学院长春应用化学研究所，研究员
· 2000.05-2003.08，美国罗彻斯特大学（University of Rochester），博士后
· 1998.10-2000.04，德国马普高分子研究所（Max-Planck-Institute for Polymer Research），洪堡访问学者
· 1998.04-1998.08，香港科技大学，访问学者
· 1996.12-1998.09，中国科学院长春应用化学研究所，助理研究员
研究方向
· 研究领域：
1、有机/高分子半导体材料及有机薄膜晶体管（OTFT）
2、有机高分子光伏材料与器件
3、共轭高分子合成方法学
承担项目
1、高性能印刷TFT半导体和绝缘层材料的设计与制备，国家重点研发计划课题（2016YFB0401101），2016/07-2020/06
2、基于芳香稠环单元的有机/高分子半导体材料的设计、合成与性能研究，国家自然科学基金重点项目（51333006），2014/01 - 2018/12
3、基于二噻吩乙烯和苯并噻二唑衍生物的D－A型共轭聚合物的合成与性能研究，国家自然科学基金面上项目（21574128），2016/01 - 2019/12
4、给体/受体薄膜纳米结构调控与器件界面调控，国家重点基础研究发展计划（973计划）子课题（2014CB643504），2014/01 - 2018/12
标志性成果
· 主要学术成就、获奖及荣誉：
1、国家"万人计划"科技创新领军人才(2016)
2、科技部中青年创新领军人才（2013）
3、国务院政府特殊津贴（2011）
4、吉林省青年科技奖（2007）
5、国家杰出青年基金（2005）
6、中国科学院百人计划 (2003)
7、吉林省科技进步一等奖（2007，排名第三）
8、国家自然科学二等奖（2009，排名第三）
· 发表论文
1. Tian Du, Ruiheng Gao, Yunfeng Deng,* Cheng Wang, Qian Zhou, Yanhou Geng,* Indandione‐terminated Quinoids:Facile Synthesis by Alkoxide‐mediated Rearrangement Reaction and Semiconducting Properties,Angew. Chem. Int. Ed.,2019, DOI: 10.1002/anie.201911530.
2. Zhongli Wang, Xianneng Song, Yu Jiang, Jidong Zhang, Xi Yu, Yunfeng Deng, Yang Han,* Wenping Hu, Yanhou Geng,* A Simple Structure Conjugated Polymer for High Mobility Organic Thin Film Transistors Processed from Nonchlorinated Solvent,Adv. Sci.2019, DOI: 10.1002/advs.201902412.
3. Qian Zhou, Yu Jiang, Tian Du, Zhongli Wang, Ziqi Liang, Yang Han,* Yunfeng Deng, Hongkun Tian, Yanhou Geng,* Diketopyrrolopyrrole-based small molecules for solution-processed n-channel organic thin film transistors, J. Mater. Chem. C,2019, DOI: 10.1039/C9TC05038H.
4. Xiafei Cheng, Miaomiao Li,* Ziqi Guo, Jinde Yu, Guanghao Lu, Laju Bu, Long Ye, Harald Ade, Yongsheng Chen, Yanhou Geng,* “Twisted” conjugated molecules as donor materials for efficient all-small-molecule organic solar cells processed with tetrahydrofuran,J. Mater. Chem. A,2019,7, 23008-23018
5. Kai Guo, Botao Wu, Yu Jiang, Zhongli Wang, Ziqi Liang, Yuning Li, Yunfeng Deng,* Yanhou Geng, Synthesis of an isomerically pure thienoquinoid for unipolar n-type conjugated polymers: effect of backbone curvature on charge transport performance,J. Mater. Chem. C,2019,7, 10352-10359.
6. Ying Sui, Yunfeng Deng,* Tian Du, Yibo Shi, Yanhou Geng,* Design strategies of n-type conjugated polymers for organic thin-film transistors,Mater. Chem. Front.,2019,3, 1932-1951.
7. Qi Wang, Miaomiao Li,* Ying Sui, Zhongli Wang, Ziqi Liang, Yanhou Geng,* Side-chain engineering of wide-bandgap polymers based on benzo[1,2-b:4,5-b’]dithiophene and [2,2’-bithiophene]-4,4’-dicarboxylate for fullerene-free organic solar cells,J. Mater. Chem. C,2019,7, 9581-9590.
8. Qi Wang, Miaomiao Li,* Xiaowei Zhang, Yunpeng Qin, Junke Wang, Jidong Zhang, Jianhui Hou, René A. J. Janssen, Yanhou Geng,* Carboxylate-Substituted Polythiophenes for Efficient Fullerene-Free Polymer Solar Cells: The Effect of Chlorination on Their Properties,Macromolecules,2019,52, 4464-4474.
9. Xiaowei Zhang, Qi Wang, Ziqi Liang, Miaomiao Li,* Yanhou Geng, Low-bandgap non-fullerene acceptors based on selenophene π-spacer and alkylated indaceno[1,2-b:5,6-b’]dithiophene for organic solar cells,Org. Electron., 2019,69, 200-207.
10. Keqiang He, Shujun Zhou, Weili Li, Hongkun Tian,* Qingxin Tang,* Jidong Zhang, Donghang Yan, Yanhou Geng,* Fosong Wang, Five-ring-fused asymmetric thienoacenes for high mobility organic thin-film transistors: the influence of the position of the S atom in the terminal thiophene ring,J. Mater. Chem. C,2019,7, 3656-3664.
11. Kai Guo, Junhua Bai, Yu Jiang, Zhongli Wang, Ying Sui, Yunfeng Deng,* Yang Han, Hongkun Tian, Yanhou Geng,* Diketopyrrolopyrrole-Based Conjugated Polymers Synthesized via Direct Arylation Polycondensation for High Mobility Pure n-Channnel Organic Field-Effect Transistors, Adv. Funct. Mater., 2018,28, 1801097.
12. Ying Sui, Yunfeng Deng,* Yang Han, Jidong Zhang, Wenping Hu, Yanhou Geng,* n-Type conjugated polymers based on 3,3’-dicyano-2,2’-bithiophene: synthesis and semiconducting properties,J. Mater. Chem. C,2018,6, 12896-12903.
13. Yao Gao, Junhua Bai, Ying Sui, Yang Han, Yunfeng Deng,* Hongkun Tian, Yanhou Geng,* Fosong Wang,Macromolecules,2018,51, 8752-8760.
14. Fangzheng Chen, Yu Jiang, Ying Sui, Jidong Zhang, Hongkun Tian, Yang Han, Yunfeng Deng, Wenping Hu, Yanhou Geng, Donor–Acceptor Conjugated Polymers Based on Bisisoindigo: Energy Level Modulation toward Unipolar n-Type Semiconductors,Macromolecules,2018,51, 8652-8661.
15. Kai Guo, Junhua Bai, Yu Jiang, Zhongli Wang, Ying Sui, Yunfeng Deng*,Yang Han, Hongkun Tian, Yanhou Geng*, Diketopyrrolopyrrole-based conjugated polymers synthesized via direct arylation polycondensation for high mobility pure n-channel organic field-effect transistors; Adv. Funct. Mater., 2018,28, 1801097.
16. Yu Jiang, Xiaohua Zheng, Yunfeng Deng, Hongkun Tian,* Junqiao Ding,* Zhigang Xie, Yanhou Geng,* and Fosong Wang, Fused Isoindigo Ribbons with Absorption Bands Reaching Near-Infrared, Angew. Chem. Int. Ed., 2018,57, 10283-10287
17. Ziqi Liang, Miaomiao Li,* Xiaomei Zhang, Qi Wang, Yu Jiang, Hongkun Tian, Yanhou Geng, Near-infrared absorbing non-fullerene acceptors with selenophene as p bridge for efficient organic solar cells, J. Mater. Chem. A, 2018, 5, 20473-20481.
18. Yingying Fu, Jianfei Qu, Yanhou Geng,* Bei Wang, Yanchun Han, Zhiyuan Xie,* Insight into correlation between molecular length and exciton dissociation, charge transport and recombination in Polymer: Oligomer based solar cells, Org. Electronics, 2018, 57, 359-366.
19. Keqiang He, Weili Li, Hongkun Tian,* Jidong Zhang, Donghang Yan, Yanhou Geng,*, Fosong Wang, Asymmetric conjugated oligomers based on polycyclic aromatics as high mobility semiconductors: the influence of chalcogens, Org. Electronics ,2018, 58, 75-81.
20. Yang Min, Chuandong Dou,* Hongkun Tian, Yanhou Geng, Jun Liu,* Lixiang Wang, n-Type Azaacenes Containing B - N Units, Angew. Chem. Int. Ed. 2018, 57, 2000-2004.
21. Qi Wang, Xin Dong, Mu He, Miaomiao Li,* Hongkun Tian, Jun Liu, Yanhou Geng,* Polythiophenes with carboxylate side chains and vinylene linkers in main chain for polymer solar cells, Polymer, 2018, 140, 89-95.
22. Hao Song, Yunfeng Deng,* Yu Jiang, Hongkun Tian, Donghang Yan, Yanhou Geng, p-Conjugation expanded isoindigo derivatives and the donor-acceptor conjugated polymers: synthesis and characterization, Chem. Commun. 2018, 54(7), 782-785.
23. 江宇，高垚，田洪坤，丁军桥*，耿延候*，王佛松，基于氟代异靛蓝并[7,6-g]异靛蓝的共轭聚合物的合成及其半导体性质，高分子学报，2017 (7)， 1141-1149。(庆祝《高分子学报》创刊60周年专辑)
24. Mu He, Miaomiao Li, Xin Dong, Hongkun Tian,* Hui Tong,* Jun Liu, Zhiyuan Xie, Yanhou Geng,* Fosong Wang, A difluorobenzothiadiazole-based conjugated polymer with alkylthiophene as the side chains for efficient, additive-free and thick-film polymer solar cells, J. Mater. Chem. A, 2017, 5, 20473–20481.
25. Keqiang He, Weili Li, Hongkun Tian,* Jidong Zhang, Donghang Yan, Yanhou Geng,* Fosong Wang, Asymmetric Conjugated Molecules Based on [1]Benzothieno[3,2 b][1]benzothiophene for High-Mobility Organic Thin-Film Transistors: Influence of Alkyl Chain Length, ACS Appl. Mater. Interfaces, 2017, 9, 35427-35436.
26. Hao Song, Yunfeng Deng,* Yao Gao, Yu Jiang, Hongkun Tian, Donghang Yan, Yanhou Geng,* Fosong Wang, Donor-Acceptor Conjugated Polymers Based on Indacenodithiophene Derivatives Bridged Diketopyrrolopyrroles: Synthesis and Semiconducting Properties, Macromolecules , 2017, 50, 2344-2353.
27. Yao Gao, Yunfeng Deng, HongkunTian,* Jidong Zhang, Donghang Yan, Yanhou Geng,* Fosong Wang, Multi-Fluorination toward High MobilityAmbipolar and Unipolar n-Type Donor-Acceptor Conjugated Polymers Based on Isoindigo, Adv. Mater. 2017, 29(13), 1606217.
28. Xin Dong, Hongkun Tian,* Zhiyuan Xie,Yanhou Geng,* Fosong Wang, Donor-Acceptor Conjugated Polymers Based on Two-Dimensional ThiopheneDerivatives for Bulk Heterojunction Solar Cells, Polym. Chem. 2017, 8, 421-430.
29. Qian Du, Jing Shao, Yao Gao, Weili Li, Hongkun Tian, Donghang Yan, Yanhou Geng,* Fosong Wang, Acceptor-Donor-Acceptor Conjugated Oligomers Based on Diketopyrrolopyrrole and Thienoacenes with Four, Five and Six Rings for Organic Thin-film Transistors, Chin. J. Polym. Sci. 2017, 35, 480-489.
30. Yingying Fu, Bei Wang, Jianfei Qu, Yang Wu, Wei Ma,* Yanhou Geng,* Yanchun Han, Zhiyuan Xie*, Fullerene-Free Polymer Solar Cells with Open-Circuit Voltage above 1.2 V: Tuning Phase Separation Behavior with Oligomer to Replace Polymer Acceptor, Adv. Funct. Mater. 2016, 26, 5922-5929.
31. Yu Jiang, Yao Gao, Hongkun Tian,* Junqiao Ding,* Donghang Yan, Yanhou Geng,* Fosong Wang, Synthesis and Characterization of Isoindigo[7,6-g]isoindigo-Based Donor-Acceptor Conjugated Polymers, Macromolecules 2016, 49, 2135-2144.
32. Mu He, Weili Li, Yao Gao, Hongkun Tian,* Jidong Zhang, Hui Tong,* Donghang Yan, Yanhou Geng,* Fosong Wang, Donor-Acceptor Conjugated Polymers Based on Dithieno[3,2-b:3¢,2¢-b¢]naphtho[1,2-b:5,6-b¢]dithiophene: Synthesis and Semiconducting Properties, Macromolecules 2016, 49(3), 825-832.
33. 董少强，田洪坤，耿延候*，王佛松，二辛基酞菁氧钒的合成、表征和半导体性质，科学通报，2016，61(3)，315-324.
34. Yao Gao, Xiaojie Zhang,* Hongkun Tian,* Jidong Zhang, Donghang Yan, Yanhou Geng,* Fosong Wang, High Mobility Ambipolar Diketopyrrolopyrrole-Based Conjugated Polymer Synthesized Via Direct Arylation Polycondensation, Adv. Mater. 2015, 27(42), 6753-6759.
35. Xin Dong, Yunfeng Deng, Hongkun Tian,* Zhiyuan Xie, Yanhou Geng,* Fosong Wang, Isoindigo-Based Low Bandgap Conjugated Polymer for o-Xylene Processed Efficient Polymer Solar Cells with Thick Active Layers, J. Mater. Chem. A 2015, 3(39), 19928-19935.
36. Hao Song, Yao Gao, Weili Li, Hongkun Tian,* Donghang Yan, Yanhou Geng,* Fosong Wang, Synthesis and Characterization of Diketopyrrolopyrrole-Based Conjugated Molecules Flanked by Indenothiophene and Benzoindenothiophene Derivatives, J. Mater. Chem. C 2015, 3, 11135-11143.
37. Jing Shao, Xiaojie Zhang, Hongkun Tian,* Yanhou Geng,* Fosong Wang, Donor-acceptor-donor conjugated oligomers based on isoindigo and anthra[1,2-b]thieno[2,3-d]thiophene for organic thin-film transistors: effect of alkyl side chain length on semiconducting properties, J. Mater. Chem. C 2015, 3, 7567-7574.
38. Aiguo Sui, Xincui Shi, Yongxia Wang, Yanhou Geng,* Fosong Wang, Kumada Catalyst Transfer Polycondensation for Controlled Synthesis of Polyfluorenes Using 1,3-Bis(diarylphosphino)propanes as Ligands, Polym. Chem. 2015, 6, 4819-4827.
39. Ziqing Rong, Yunfeng Deng, Zhiyuan Xie, Yanhou Geng,* Fosong Wang, Dithienocarbazole and Benzothiadiazole Based Donor-Acceptor Conjugated Polymers for Bulk Heterojunction Polymer Solar Cells, Sci. China Chem. 2015, 58, 294-300.
40. Xincui Shi, Aiguo Sui, Yongxia Wang, Yuesheng Li, Yanhou Geng,* Fosong Wang, Controlled Synthesis of High Molecular Weight Poly(3-hexylthiophene)s via Kumada Catalyst Transfer Polycondensation with Ni(IPr)(acac)2 as the Catalyst, Chem. Commun. 2015, 51, 2138-2140.
41. Yunfeng Deng, Weili Li, Lihui Liu, Hongkun Tian,* Zhiyuan Xie, Yanhou Geng*, Fosong Wang, Low Bandgap Conjugated Polymers Based on Mono-Fluorinated Isoindigo for Efficient Bulk Heterojunction Polymer Solar Cells Processed with Non-Chlorinated Solvent, Energy Environ. Sci. 2015, 8, 585-591.
42. Jing Shao, Xiaoli Zhang, Li Wang, Qingxin Tang, Weili Li, Han Yu, Hongkun Tian, Xiaojie Zhang*, Yanhou Geng*, Fosong Wang, Synthesis and characterization of pi-extended thienoacenes with up to 13 fused aromatic rings, Tetrahedron. Lett. 2014, 55, 5663-5666.
43. Xiaojie Zhang*, Yao Gao, Sida Li, Xincui Shi, Yanhou Geng, Fosong Wang, Synthesis of Poly(5,6-difluoro-2,1,3-benzothiadiazole-alt-9,9-dioctylfluorene) via Direct Arylation Polycondensation, J. Polym. Sci. Polym. Chem. 2014, 52, 2367-2374.
44. Aiguo Sui, Xincui Shi, Hongkun Tian, Yanhou Geng*, Fosong Wang, Suzuki-Miyaura Catalyst-Transfer Polycondensation with Pd(IPr)(OAc)2 as the Catalyst for the Controlled Synthesis of Polyfluorenes and Polythiophenes, Polym. Chem. 2014, 5, 7072-7080.
45. Yuanyuan Han, Yan Guo, Yingfei Chang, Yanhou Geng, Zhaohui Su*, Chain Folding in Poly(3-hexylthiophene) Crystals, Macromolecules 2014, 47, 3708-3712.
46. Jian Liu, Jiang Wu, Shuyan Shao, Yunfeng Deng, Bin Meng, Zhiyuan Xie*, Yanhou Geng, Lixiang Wang, Fengling Zhang, Printable Highly Conductive Conjugated Polymer Sensitized ZnO NCs as Cathode Interfacial Layer for Efficient Polymer Solar Cells, ACS Appl. Mater. Interfaces 2014, 6, 8237-8245.
47. Li Wang, Xiaojie Zhang, Jidong Zhang, Hongkun Tian, Yunfeng Lu*, Yanhou Geng*, Fosong Wang, Synthesis and Characterization of Oligo(2,5-bis(3-dodecylthiophen-2-yl)thieno[3,2-b]thiophene)s: Effect of the Chain Length and End-Groups on Their Optical and Charge Transport Properties, J. Mater. Chem. C 2014, 2, 9978-9986.
48. Jianfei Qu, Bingrong Gao, Hongkun Tian, Xiaojie Zhang, Yan Wang, Zhiyuan Xie*, Haiyu Wang, Yanhou Geng*, Fosong Wang, Donor-Spacer-Acceptor Monodisperse Conjugated Co-Oligomers for Efficient Single-Molecule Photovoltaic Cells Based on Non-Fullerene Acceptors, J. Mater. Chem. A 2014, 2, 3632-3640.
49. Hongkun Tian*, Yagang Chen, Weili Li, Donghang Yan, Yanhou Geng*, Fosong Wang, Synthesis, characterization and semiconducting properties of oligo(2,6-naphthalene)s, Org. Electron. 2014, 15, 1088-1095.
50. Han Yu, Weili Li, Hongkun Tian*, Haibo Wang, Donghang Yan, Jingping Zhang*, Yanhou Geng*, Fosong Wang, Benzothienobenzothiophene-Based Conjugated Oligomers as Semiconductors for Stable Organic Thin-Film Transistors, ACS Appl. Mater. Interfaces 2014, 6, 5255-5262.
51. Yunfeng Deng, Jian Liu, Jiantai Wang, Lihui Liu, Weili Li, HongkunTian, Xiaojie Zhang, ZhiyuanXie*, YanhouGeng*, Fosong Wang, Dithienocarbazole and isoindigo based amorphous low bandgap conjugated polymers for efficient polymer solar cells, Adv. Mater. 2014, 26, 471-476.