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耿延候 教授

先进高分子材料研究所

电话: 022-27402307

Email: yanhou.geng@tju.edu.cn

研究所: 先进高分子材料研究所

个人简历

2015.12-现在,  天津大学材料科学与工程学院,教授
2003.09-2015.11,中国科学院长春应用化学研究所,研究员
2000.05-2003.08,美国罗彻斯特大学(University of Rochester),博士后
1998.10-2000.04,德国马普高分子研究所(Max-Planck-Institute for Polymer Research),洪堡访问学者
1998.04-1998.08,香港科技大学,访问学者
1996.12-1998.09,中国科学院长春应用化学研究所,助理研究员

研究方向

(1)有机/高分子半导体材料及有机薄膜晶体管(OTFT)
(2)有机高分子光伏材料与器件
(3)共轭高分子合成方法学

承担项目

1、高性能印刷TFT 半导体和绝缘层材料的设计与制备,国家重点研发计划课题(2016YFB0401101),2016/07-2020/06
2、基于芳香稠环单元的有机/高分子半导体材料的设计、合成与性能研究,国家自然科学基金重点项目(51333006),2014/01 - 2018/12
3、基于二噻吩乙烯和苯并噻二唑衍生物的D-A型共轭聚合物的合成与性能研究,国家自然科学基金面上项目(21574128),2016/01 - 2019/12
4、给体/受体薄膜纳米结构调控与器件界面调控,国家重点基础研究发展计划(973计划)子课题(2014CB643504),2014/01 - 2018/12

标志性成果

主要学术成就、获奖及荣誉:
国家"万人计划"科技创新领军人才(2016)
科技部中青年创新领军人才(2013)
国务院政府特殊津贴(2011)
吉林省青年科技奖(2007)
国家杰出青年基金(2005)
中国科学院百人计划 (2003)
吉林省科技进步一等奖(2007,排名第三)
国家自然科学二等奖(2009,排名第三)

近5年发表文章:

2018

1. Kai Guo, Junhua Bai, Yu Jiang, Zhongli Wang, Ying Sui, Yunfeng Deng,* Yang Han, Hongkun Tian, Yanhou Geng,* Diketopyrrolopyrrole-Based Conjugated Polymers Synthesized via Direct Arylation Polycondensation for High Mobility Pure n-Channnel Organic Field-Effect Transistors, Adv. Funct. Mater. 2018, DOI:adfm.201801097.

2. Yu Jiang, Xiaohua Zheng, Yunfeng Deng, Hongkun Tian,* Junqiao Ding,* Zhigang Xie, Yanhou Geng,* Fosong Wang, Fused isoindigo ribbons with absorption bands reaching near-infrared, Angew. Chem. Int. Ed. 2018DOI:10.1002/anie.20180051

3. Ziqi Liang, Miaomiao Li,* Xiaomei Zhang, Qi Wang, Yu Jiang, Hongkun Tian, Yanhou Geng, Near-infrared absorbing non-fullerene acceptors with selenophene as p bridge for efficient organic solar cells, J. Mater. Chem. A 2018, 5, 20473-20481. 

180. Yingying Fu, Jianfei Qu, Yanhou Geng,* Bei Wang, Yanchun Han, Zhiyuan Xie,* Insight into correlation between molecular length and exciton dissociation, charge transport and recombination in Polymer: Oligomer based solar cells, Org. Electronics 2018, 57, 359-366.

4. Keqiang He, Weili Li, Hongkun Tian,* Jidong Zhang, Donghang Yan, Yanhou Geng,*, Fosong Wang, Asymmetric conjugated oligomers based on polycyclic aromatics as high mobility semiconductors: the influence of chalcogens, Org. Electronics 2018, 58, 75-81.

5. Yang Min, Chuandong Dou,* Hongkun Tian, Yanhou Geng, Jun Liu,* Lixiang Wang, n-Type Azaacenes Containing B - N Units, Angew. Chem. Int. Ed. 2018, 57(7), 2000-2004.

6. Qi Wang, Xin Dong, Mu He, Miaomiao Li,* Hongkun Tian, Jun Liu, Yanhou Geng,* Polythiophenes with carboxylate side chains and vinylene linkers in main chain for polymer solar cells, Polymer, 2018, 140, 89-95.

7. Hao Song, Yunfeng Deng,* Yu Jiang, Hongkun Tian, Donghang Yan, Yanhou Geng, p-Conjugation expanded isoindigo derivatives and the donor-acceptor conjugated polymers: synthesis and characterization, Chem. Commun. 2018, 54(7), 782-785.

2017

8. 江宇,高垚,田洪坤,丁军桥*,耿延候*,王佛松,基于氟代异靛蓝并[7,6-g]异靛蓝的共轭聚合物的合成及其半导体性质,高分子学报,2017 (7) 1141-1149(庆祝《高分子学报》创刊60周年专辑)

9. Mu He, Miaomiao Li, Xin Dong, Hongkun Tian,* Hui Tong,* Jun Liu, Zhiyuan Xie, Yanhou Geng,* Fosong Wang, A difluorobenzothiadiazole-based conjugated polymer with alkylthiophene as the side chains for efficient, additive-free and thick-film polymer solar cells, J. Mater. Chem. A 2017, 5, 20473–20481.

10. Keqiang He, Weili Li, Hongkun Tian,* Jidong Zhang, Donghang Yan, Yanhou Geng,* Fosong Wang, Asymmetric Conjugated Molecules Based on [1]Benzothieno[3,2b][1]benzothiophene for High-Mobility Organic Thin-Film Transistors: Influence of Alkyl Chain Length, ACS Appl. Mater. Interfaces 2017, 9, 35427-35436.

11. Hao Song, Yunfeng Deng,* Yao Gao, Yu Jiang, Hongkun Tian, Donghang Yan, Yanhou Geng,* Fosong Wang, Donor-Acceptor Conjugated Polymers Based on Indacenodithiophene Derivatives Bridged Diketopyrrolopyrroles: Synthesis and Semiconducting Properties, Macromolecules 2017, 50, 2344-2353.

12. Yao Gao, Yunfeng Deng, HongkunTian,* Jidong Zhang, Donghang Yan, Yanhou Geng,* Fosong Wang, Multi-Fluorination toward High MobilityAmbipolar and Unipolar n-Type Donor-Acceptor Conjugated Polymers Based on Isoindigo, Adv. Mater. 2017, 29(13), 1606217.

13. Xin Dong, Hongkun Tian,* Zhiyuan Xie,Yanhou Geng,* Fosong Wang, Donor-Acceptor Conjugated Polymers Based on Two-Dimensional ThiopheneDerivatives for Bulk Heterojunction Solar Cells, Polym. Chem. 2017, 8, 421-430.

14. Qian Du, Jing Shao, Yao Gao, Weili Li, Hongkun Tian, Donghang Yan, Yanhou Geng,* Fosong Wang, Acceptor-Donor-Acceptor Conjugated Oligomers Based on Diketopyrrolopyrrole and Thienoacenes with Four, Five and Six Rings for Organic Thin-film Transistors, Chin. J. Polym. Sci. 2017, 35, 480-489.

2016

15. Yingying Fu, Bei Wang, Jianfei Qu, Yang Wu, Wei Ma,* Yanhou Geng,* Yanchun Han, Zhiyuan Xie*, Fullerene-Free Polymer Solar Cells with Open-Circuit Voltage above 1.2 V: Tuning Phase Separation Behavior with Oligomer to Replace Polymer Acceptor, Adv. Funct. Mater. 2016, 26, 5922-5929.

16. Yu Jiang, Yao Gao, Hongkun Tian,* Junqiao Ding,* Donghang Yan, Yanhou Geng,* Fosong Wang, Synthesis and Characterization of Isoindigo[7,6-g]isoindigo-Based Donor-Acceptor Conjugated Polymers, Macromolecules 2016, 49, 2135-2144.

17. Mu He, Weili Li, Yao Gao, Hongkun Tian,* Jidong Zhang, Hui Tong,* Donghang Yan, Yanhou Geng,* Fosong Wang, Donor-Acceptor Conjugated Polymers Based on Dithieno[3,2-b:3¢,2¢-b¢]naphtho[1,2-b:5,6-b¢]dithiophene: Synthesis and Semiconducting Properties, Macromolecules 2016, 49(3), 825-832.

18. 董少强,田洪坤,耿延候*,王佛松,二辛基酞菁氧钒的合成、表征和半导体性质,科学通报,201661(3)315-324.

2015

19. Yao Gao, Xiaojie Zhang,* Hongkun Tian,* Jidong Zhang, Donghang Yan, Yanhou Geng,* Fosong Wang, High Mobility Ambipolar Diketopyrrolopyrrole-Based Conjugated Polymer Synthesized Via Direct Arylation Polycondensation, Adv. Mater. 2015, 27(42), 6753-6759.

20. Xin Dong, Yunfeng Deng, Hongkun Tian,* Zhiyuan Xie, Yanhou Geng,* Fosong Wang, Isoindigo-Based Low Bandgap Conjugated Polymer for o-Xylene Processed Efficient Polymer Solar Cells with Thick Active Layers, J. Mater. Chem. A 2015, 3(39), 19928-19935.

21. Hao Song, Yao Gao, Weili Li, Hongkun Tian,* Donghang Yan, Yanhou Geng,* Fosong Wang, Synthesis and Characterization of Diketopyrrolopyrrole-Based Conjugated Molecules Flanked by Indenothiophene and Benzoindenothiophene Derivatives, J. Mater. Chem. C 2015, 3(42), 11135-11143.

22. Jing Shao, Xiaojie Zhang, Hongkun Tian,* Yanhou Geng,* Fosong Wang, Donor-acceptor-donor conjugated oligomers based on isoindigo and anthra[1,2-b]thieno[2,3-d]thiophene for organic thin-film transistors: effect of alkyl side chain length on semiconducting properties, J. Mater. Chem. C 2015, 3(29), 7567-7574.

23. Aiguo Sui, Xincui Shi, Yongxia Wang, Yanhou Geng,* Fosong Wang, Kumada Catalyst Transfer Polycondensation for Controlled Synthesis of Polyfluorenes Using 1,3-Bis(diarylphosphino)propanes as Ligands, Polym. Chem. 2015, 6(26), 4819-4827.

24. Ziqing Rong, Yunfeng Deng, Zhiyuan Xie, Yanhou Geng,* Fosong Wang, Dithienocarbazole and Benzothiadiazole Based Donor-Acceptor Conjugated Polymers for Bulk Heterojunction Polymer Solar Cells, Sci. China Chem. 2015, 58, 294-300.

25. Xincui Shi, Aiguo Sui, Yongxia Wang, Yuesheng Li, Yanhou Geng,* Fosong Wang, Controlled Synthesis of High Molecular Weight Poly(3-hexylthiophene)s via Kumada Catalyst Transfer Polycondensation with Ni(IPr)(acac)2 as the Catalyst, Chem. Commun. 2015, 51, 2138-2140.

26. Yunfeng Deng, Weili Li, Lihui Liu, Hongkun Tian,* Zhiyuan Xie, Yanhou Geng*, Fosong Wang, Low Bandgap Conjugated Polymers Based on Mono-Fluorinated Isoindigo for Efficient Bulk Heterojunction Polymer Solar Cells Processed with Non-Chlorinated Solvent, Energy Environ. Sci. 2015, 8, 585-591.

2014

27. Jing Shao, Xiaoli Zhang, Li Wang, Qingxin Tang, Weili Li, Han Yu, Hongkun Tian, Xiaojie Zhang*, Yanhou Geng*, Fosong Wang, Synthesis and characterization of pi-extended thienoacenes with up to 13 fused aromatic rings, Tetrahedron. Lett. 2014, 55, 5663-5666.

28. Xiaojie Zhang*, Yao Gao, Sida Li, Xincui Shi, Yanhou Geng, Fosong Wang, Synthesis of Poly(5,6-difluoro-2,1,3-benzothiadiazole-alt-9,9-dioctylfluorene) via Direct Arylation Polycondensation, J. Polym. Sci. Polym. Chem. 2014, 52, 2367-2374.

29. Aiguo Sui, Xincui Shi, Hongkun Tian, Yanhou Geng*, Fosong Wang, Suzuki-Miyaura Catalyst-Transfer Polycondensation with Pd(IPr)(OAc)2 as the Catalyst for the Controlled Synthesis of Polyfluorenes and Polythiophenes, Polym. Chem. 2014, 5, 7072-7080.

30. Yuanyuan Han, Yan Guo, Yingfei Chang, Yanhou Geng, Zhaohui Su*, Chain Folding in Poly(3-hexylthiophene) Crystals, Macromolecules 2014, 47, 3708-3712.

31. Jian Liu, Jiang Wu, Shuyan Shao, Yunfeng Deng, Bin Meng, Zhiyuan Xie*, Yanhou Geng, Lixiang Wang, Fengling Zhang, Printable Highly Conductive Conjugated Polymer Sensitized ZnO NCs as Cathode Interfacial Layer for Efficient Polymer Solar Cells, ACS Appl. Mater. Interfaces 2014, 6, 8237-8245.

32. Li Wang, Xiaojie Zhang, Jidong Zhang, Hongkun Tian, Yunfeng Lu*, Yanhou Geng*, Fosong Wang, Synthesis and Characterization of Oligo(2,5-bis(3-dodecylthiophen-2-yl)thieno[3,2-b]thiophene)s: Effect of the Chain Length and End-Groups on Their Optical and Charge Transport Properties, J. Mater. Chem. C 2014, 2, 9978-9986.

33. Jianfei Qu, Bingrong Gao, Hongkun Tian, Xiaojie Zhang, Yan Wang, Zhiyuan Xie*, Haiyu Wang, Yanhou Geng*, Fosong Wang, Donor-Spacer-Acceptor Monodisperse Conjugated Co-Oligomers for Efficient Single-Molecule Photovoltaic Cells Based on Non-Fullerene Acceptors, J. Mater. Chem. A 2014, 2, 3632-3640.

34. Hongkun Tian*, Yagang Chen, Weili Li, Donghang Yan, Yanhou Geng*, Fosong Wang, Synthesis, characterization and semiconducting properties of oligo(2,6-naphthalene)s, Org. Electron. 2014, 15, 1088-1095.

35. Han Yu, Weili Li, Hongkun Tian*, Haibo Wang, Donghang Yan, Jingping Zhang*, Yanhou Geng*, Fosong Wang, Benzothienobenzothiophene-Based Conjugated Oligomers as Semiconductors for Stable Organic Thin-Film Transistors, ACS Appl. Mater. Interfaces 2014, 6, 5255-5262.

36. Yunfeng Deng, Jian Liu, Jiantai Wang, Lihui Liu, Weili Li, HongkunTian, Xiaojie Zhang, ZhiyuanXie*, YanhouGeng*, Fosong Wang, Dithienocarbazole and isoindigo based amorphous low bandgap conjugated polymers for efficient polymer solar cells, Adv. Mater. 2014, 26, 471-476.

2013

37. Li Wang, Xiaojie Zhang, Hongkun Tian, Yunfeng Lu*, Yanhou Geng*, Fosong Wang, A Cyano-Terminated Dithienyl Diketopyrrolopyrrole Dimer as a Solution Processable Ambipolar Semiconductor under Ambient Conditions, Chem. Commun. 2013, 49, 11272-11274.

38. Bingrong Gao, Jianfei Qu, Yan Wang, Yingying Fu, Lei Wang, Qidai Chen, Hongbo Sun, Yanhou Geng, Haiyu Wang*, Zhiyuan Xie*, Femtosecond Spectroscopic Study of Photoinduced Charge Separation and Recombination in the Donor-Acceptor Co-Oligomers for Solar Cells, J. Phy. Chem. C. 2013, 117, 4836-4843.

39. Yunfeng Deng, Yagang Chen, Jian Liu, Lihui Liu, Hongkun Tian, Zhiyuan Xie, Yanhou Geng*, Fosong Wang, Low-Band-Gap Conjugated Polymers of Dithieno[2,3-b:7,6-b]carbazole and Diketopyrrolopyrrole: Effect of the Alkyl Side Chain on Photovoltaic Properties, ACS Appl. Mater. Interfaces 2013, 5, 5741-5747.

40. Chengfang Liu, Aiguo Sui, Qilin Wang, Hongkun Tian, Yanhou Geng, Donghang Yan*, Fractionated crystallization of polydisperse polyfluorenes, Polymer 2013, 54, 3150-3155.

41. Chengfang Liu, Qilin Wang, Hongkun Tian, Yanhou Geng, Donghang Yan*, Extended-chain lamellar crystals of monodisperse polyfluorenes, Polymer 2013, 54, 2459-2465.

42. Chengfang Liu, Qilin Wang, Hongkun Tian, Jian Liu, Yanhou Geng, Donghang Yan*, Insight into lamellar crystals of monodisperse polyfluorenes - Fractionated crystallization and the crystal's stability, Polymer 2013, 54, 1251-1258.

43. Jiangang Liu, Yue Sun, Lidong Zheng, Yanhou Geng, Yanchun Han*, Vapor-assisted imprinting to pattern poly(3-hexylthiophene) (P3HT) film with oriented arrangement of nanofibrils and flat-on conformation of P3HT chains, Polymer 2013, 54, 423-430.

44. Chengfang Liu, Qilin Wang, Hongkun Tian, Jian Liu, Yanhou Geng, Donghang Yan*, Morphology and Structure of the beta Phase Crystals of Monodisperse Polyfluorenes, Macromolecules 2013, 46, 3025-3030.

45. Chengfang Liu, Qilin Wang, Hongkun Tian, Jian Liu, Yanhou Geng, Donghang Yan*, Control of Crystal Morphology in Monodisperse Polyfluorenes by Solvent and Molecular Weight, J. Phy. Chem. B. 2013, 117, 8880-8886.

46. 邓云峰,鲍程,田洪坤,谢志元,耿延候*,含二噻吩并[3,2-b2,3-d]氧膦杂环戊二烯共轭聚合物的合成及其在薄膜晶体管和体异质结太阳能电池中的应用,高分子学报, 2013, 609-618.

47. Jianfei Qu, Jian Liu, Sida Li, Zhiyuan Xie, Yanhou Geng*, Donor-Acceptor Conjugated Cooligomers for Single Molecule Solar Cells, Chin. J. Polym. Sci. 2013, 31, 815-822.

48. Shaoqiang Dong, Cheng Bao, Hongkun Tian,* Donghang Yan, Yanhou Geng, Fosong Wang, ABAB-Symmetric Tetraalkyl Titanyl Phthalocyanines for Solution Processed Organic Field-Effect Transistors with Mobility Approaching 1 cm2V-1s-1, Adv. Mater. 2013, 25, 1165-1169.